Selected Publications
Selected Publications
Embedded Files
2025
2025
Impact of Non-Polar Solvents in Dynamic Nuclear Polarization at High Magnetic FieldsT. Orlando, H. Bui, J. Cabigting, N. Ibbetson, J. van Tol, T. Dubroca, X. Wang, F. Mentink-VigierJournal of Magnetic Resonance, 107885. Link
Halogen-Bond-Mediated 13C Overhauser Dynamic Nuclear Polarization at 9.4 TL. Yang, T. Orlando, M. BennatiThe Journal of Physical Chemistry Letters 16, 4505-4514. Link
Halogen-Bond-Mediated 13C Overhauser Dynamic Nuclear Polarization at 9.4 TL. Yang, T. Orlando, M. BennatiThe Journal of Physical Chemistry Letters 16, 4505-4514. Link
Nanoparticle-assisted Dynamic Nuclear Polarization in Liquids
B.B. Mascitti, G. Zanoni, A. van der Ham, L. Yang, L. Franco, F. Mancin, F. Rastrelli, T. Orlando
Physical Chemistry Chemical Physics, DOI:10.1039/D5CP02465J. Link
An All-O-Donor Family of Mn(II) and Mn(III) Complexes with Perfluorinated Alkoxide LigandsS. M. Moore, C. Sun, Y. Chen, S. C. Lee, V. Oswald, M. M. Turnbull, J. McNeely, A. Ozarowski, T. Orlando, A. L. Rheingold, L. H. DoerrerInorganic Chemistry 64, 20688-20704. Link
Enhancing NMR Signals in Liquids by Fluorine-19 Overhauser Dynamic Nuclear Polarization (DNP) and Hyperpolarization Transfer to Carbon-13M. Reinhard, A. van der Ham, L. Yang, L. Böker, T. Orlando, I. Tkach, M. Levien, M. BennatiAngewandte Chemie, e202517498, in press, Link.
Enhancing NMR Signals in Liquids by Fluorine-19 Overhauser Dynamic Nuclear Polarization (DNP) and Hyperpolarization Transfer to Carbon-13M. Reinhard, A. van der Ham, L. Yang, L. Böker, T. Orlando, I. Tkach, M. Levien, M. BennatiAngewandte Chemie, e202517498, in press, Link.
2025
2025
Nanoparticle-assisted Dynamic Nuclear Polarization in Liquids
Impact of Non-Polar Solvents in Dynamic Nuclear Polarization at High Magnetic FieldsT. Orlando, H. Bui, J. Cabigting, N. Ibbetson, J. van Tol, T. Dubroca, X. Wang, F. Mentink-VigierJournal of Magnetic Resonance, 107885. Link
Halogen-Bond-Mediated 13C Overhauser Dynamic Nuclear Polarization at 9.4 TL. Yang, T. Orlando, M. BennatiThe Journal of Physical Chemistry Letters 16, 4505-4514. Link
An All-O-Donor Family of Mn(II) and Mn(III) Complexes with Perfluorinated Alkoxide LigandsS. M. Moore, C. Sun, Y. Chen, S. C. Lee, V. Oswald, M. M. Turnbull, J. McNeely, A. Ozarowski, T. Orlando, A. L. Rheingold, L. H. DoerrerInorganic Chemistry 64, 20688-20704. Link
Enhancing NMR Signals in Liquids by Fluorine-19 Overhauser Dynamic Nuclear Polarization (DNP) and Hyperpolarization Transfer to Carbon-13M. Reinhard, A. van der Ham, L. Yang, L. Böker, T. Orlando, I. Tkach, M. Levien, M. BennatiAngewandte Chemie, in press, Link.
B.B. Mascitti, G. Zanoni, A. van der Ham, L. Yang, L. Franco, F. Mancin, F. Rastrelli, T. Orlando
Physical Chemistry Chemical Physics, DOI:10.1039/D5CP02465J. Link
Impact of Non-Polar Solvents in Dynamic Nuclear Polarization at High Magnetic FieldsT. Orlando, H. Bui, J. Cabigting, N. Ibbetson, J. van Tol, T. Dubroca, X. Wang, F. Mentink-VigierJournal of Magnetic Resonance, 107885. Link
Halogen-Bond-Mediated 13C Overhauser Dynamic Nuclear Polarization at 9.4 TL. Yang, T. Orlando, M. BennatiThe Journal of Physical Chemistry Letters 16, 4505-4514. Link
An All-O-Donor Family of Mn(II) and Mn(III) Complexes with Perfluorinated Alkoxide LigandsS. M. Moore, C. Sun, Y. Chen, S. C. Lee, V. Oswald, M. M. Turnbull, J. McNeely, A. Ozarowski, T. Orlando, A. L. Rheingold, L. H. DoerrerInorganic Chemistry 64, 20688-20704. Link
Enhancing NMR Signals in Liquids by Fluorine-19 Overhauser Dynamic Nuclear Polarization (DNP) and Hyperpolarization Transfer to Carbon-13M. Reinhard, A. van der Ham, L. Yang, L. Böker, T. Orlando, I. Tkach, M. Levien, M. BennatiAngewandte Chemie, in press, Link.
2024
2024
Overhauser Enhanced Liquid State Nuclear Magnetic Resonance Spectroscopy in One and Two DimensionsM. Levien, L. Yang, A. van der Ham, M. Reinhard, M. John, A. Purea, J. Ganz, T. Marquardsen, I. Tkach, T. Orlando, M. BennatiNature Communications 15, 5904. Link
Spin-Phonon Coupling in Iron-Doped Ultrathin Bismuth Halide Perovskite DerivativesY. Liu, Q. Ai, Z. Ye, J. Hruby, F. Wang, T. Orlando, Y. Wang, J. Luo, Q. Fang, B. Zhang, T. Zhai, C. Lin, C. Xu, Y. Zhu, T. Terlier, S. Hill, H. Zhu, R. He, J. LouAmerican Chemical Society Nano 18, 12560-12568. Link
PATENT: DNP probe head for high resolution, liquid-state NMRT. Marquardsen, M. Bennati, I. Tkach, M. Levien, T. Orlando, L. Yang, A. Leveasly, R. WyldeGerman Patent no. DE: 10 2022 212 952.0. Link
Spin-Phonon Coupling in Iron-Doped Ultrathin Bismuth Halide Perovskite DerivativesY. Liu, Q. Ai, Z. Ye, J. Hruby, F. Wang, T. Orlando, Y. Wang, J. Luo, Q. Fang, B. Zhang, T. Zhai, C. Lin, C. Xu, Y. Zhu, T. Terlier, S. Hill, H. Zhu, R. He, J. LouAmerican Chemical Society Nano 18, 12560-12568. Link
PATENT: DNP probe head for high resolution, liquid-state NMRT. Marquardsen, M. Bennati, I. Tkach, M. Levien, T. Orlando, L. Yang, A. Leveasly, R. WyldeGerman Patent no. DE: 10 2022 212 952.0. Link
2023
2023
Large 31P-NMR Enhancements in Liquid State Dynamic Nuclear Polarization through Radical/target Molecule Non-covalent interactionM. Reinhard, M. Levien, M. Bennati, T. OrlandoPhysical Chemistry Chemical Physics 25, 822-828. Link
2022
2022
Theoretical Analysis of Scalar Relaxation in 13C-DNP in LiquidsT. Orlando, I. Kuprov, M. HillerJournal of Magnetic Resonance Open 10-11, 100040. Link
2021
2021
Spin Density Localization and Accessibility in Organic Radicals for Liquid-state DNP EfficiencyM. Levien, M. Reinhard, M. Hiller, I. Tkach, M. Bennati, T. OrlandoPhysical Chemistry Chemical Physics 23, 4480–4485. Link
2020
2020
Nitroxide Derivatives for Dynamic Nuclear Polarization in Liquids: the Role of Rotational DiffusionM. Levien, M. Hiller, I. Tkach, M. Bennati, T. OrlandoThe Journal of Physical Chemistry Letters 11, 1629-1635. Link
Low Temperature Anomalies in Muon Spin Relaxation of Full and Hollow γ-Fe2O3 Nanoparticles: a Pathway to Detect Unusual Local Spin DynamicsM. Basini, S. Sanna, T. Orlando, L. Bordonali, M. Cobianchi, P. Arosio, M. Mariani, D. Peddis, V. Bonanni, R. Mathieu, T. Kalaivani, G. Singh, J. Larionova, Y. Guari, L. Lartigue, A. LascialfariPhysical Review B 102, 195424. Link
Low Temperature Anomalies in Muon Spin Relaxation of Full and Hollow γ-Fe2O3 Nanoparticles: a Pathway to Detect Unusual Local Spin DynamicsM. Basini, S. Sanna, T. Orlando, L. Bordonali, M. Cobianchi, P. Arosio, M. Mariani, D. Peddis, V. Bonanni, R. Mathieu, T. Kalaivani, G. Singh, J. Larionova, Y. Guari, L. Lartigue, A. LascialfariPhysical Review B 102, 195424. Link
2019
2019
Dynamic Nuclear Polarization of 13C nuclei in the Liquid State over a 10 Tesla Field RangeT. Orlando, R. Dervişoğlu, M. Levien, I. Tkach, T.F. Prisner, L.B. Andreas, V.P. Denysenkov, M. BennatiAngewandte Chemie 58, 1402–1406. Link
Role of Zn2+ Substitution on the Magnetic, Hyperthermic, and Relaxometric Properties of Cobalt Ferrite NanoparticlesM. Albino, E. Fantechi, C. Innocenti, A. López-Ortega, V. Bonanni, G. Campo, F. Pineider, M. Gurioli, P. Arosio, T. Orlando, G. Bertoni, C. De Julián Fernández, A. Lascialfari, C. SangregorioThe Journal of Physical Chemistry C 123, 6148–6157. Link
Role of Zn2+ Substitution on the Magnetic, Hyperthermic, and Relaxometric Properties of Cobalt Ferrite NanoparticlesM. Albino, E. Fantechi, C. Innocenti, A. López-Ortega, V. Bonanni, G. Campo, F. Pineider, M. Gurioli, P. Arosio, T. Orlando, G. Bertoni, C. De Julián Fernández, A. Lascialfari, C. SangregorioThe Journal of Physical Chemistry C 123, 6148–6157. Link
Book chapter
Overhauser DNP in Liquids on 13C NucleiM. Bennati, T. OrlandoeMagRes 8, 11–18. LinkBook chapter
inHandbook of High Field Dynamic Nuclear Polarizationed.: V. K. Michaelis, R. G. Griffin, B. Corzilius, S. VegaWiley, 2020
2018
2018
Spin Dynamics in the Single-ion Magnet [Er(W5O18)2]9−M. Mariani, F. Borsa, M.J. Graf, S. Sanna, M. Filibian, T. Orlando, S.K.P. Velu, E. Coronado, A. LascialfariPhysical Review B 97, 144414. Link
2017
2017
Local Spin Dynamics of Iron Oxide Magnetic Nanoparticles Dispersed in Different Solvents with Variable Size and Shape: A 1H NMR StudyM. Basini, T. Orlando, P. Arosio, M.F. Casula, D. Espa, S. Murgia, C. Sangregorio, C. Innocenti, A. LascialfariThe Journal of Chemical Physics 146, 034703. Link
2016
2016
NMR Relaxation Induced by Iron Oxide Particles: Testing Theoretical ModelsY. Gossuin, T. Orlando, M. Basini, D. Henrard, A. Lascialfari, C. Mattea, S. Stapf, Q.L. VuongNanotechnology 27, 155706. Link
On the Magnetic Anisotropy and Nuclear Relaxivity Effects of Co and Ni Doping in Iron Oxide NanoparticlesT. Orlando, M. Albino, F. Orsini, C. Innocenti, M. Basini, P. Arosio, C. Sangregorio, M. Corti, A. LascialfariJournal of Applied Physics 119, 134301. Link
Persistence of Slow Dynamics in Tb(OETAP)2 Single Molecule MagnetsEmbedded in Conducting PolymersT. Orlando, M. Filibian, S. Sanna, N. Giménez-Agullo, C.S. de Pipaón, P. Ballester, J.R. Galán-Mascarós, P. CarrettaJournal of Physics: Condensed Matter 28, 386002. Link
Characterization of Magnetic Nanoparticles from Magnetospirillum Gryphiswaldense as Potential Theranostics ToolsT. Orlando, S. Mannucci, E. Fantechi, G. Conti, S. Tambalo, A. Busato, C. Innocenti, L. Ghin, R. Bassi, P. Arosio, F. Orsini, C. Sangregorio, M. Corti, M.F. Casula, P. Marzola, A. Lascialfari, A. SbarbatiContrast Media & Molecular Imaging 11, 139–145. Link
On the Magnetic Anisotropy and Nuclear Relaxivity Effects of Co and Ni Doping in Iron Oxide NanoparticlesT. Orlando, M. Albino, F. Orsini, C. Innocenti, M. Basini, P. Arosio, C. Sangregorio, M. Corti, A. LascialfariJournal of Applied Physics 119, 134301. Link
Persistence of Slow Dynamics in Tb(OETAP)2 Single Molecule MagnetsEmbedded in Conducting PolymersT. Orlando, M. Filibian, S. Sanna, N. Giménez-Agullo, C.S. de Pipaón, P. Ballester, J.R. Galán-Mascarós, P. CarrettaJournal of Physics: Condensed Matter 28, 386002. Link
Characterization of Magnetic Nanoparticles from Magnetospirillum Gryphiswaldense as Potential Theranostics ToolsT. Orlando, S. Mannucci, E. Fantechi, G. Conti, S. Tambalo, A. Busato, C. Innocenti, L. Ghin, R. Bassi, P. Arosio, F. Orsini, C. Sangregorio, M. Corti, M.F. Casula, P. Marzola, A. Lascialfari, A. SbarbatiContrast Media & Molecular Imaging 11, 139–145. Link
2015
2015
Spin Dynamics in Hybrid Iron Oxide-Gold NanostructuresT. Orlando, A. Capozzi, E. Umut, L. Bordonali, M. Mariani, P. Galinetto, F. Pineider, C. Innocenti, P. Masala, F. Tabak, M. Scavini, P. Santini, M. Corti, P. Ghigna, A. LascialfariThe Journal of Physical Chemistry C 119, 1224–1233. Link
2014
2014
NMR as an Evaluation Strategy for Cellular Uptake of NanoparticlesT. Orlando, A. Paolini, F. Pineider, E. Clementi, F. Pasi, Y. Guari, J. Larionova, L. Sacchi, R. Nano, M. Corti, A. LascialfariNano Letters 14, 3959–3965. Link
2013
2013
Hybrid Iron Oxide-Copolymer Micelles and Vesicles as Contrast Agents for MRI: Impact of the Nanostructure on the Relaxometric PropertiesP. Arosio, J. Thévenot, T. Orlando, F. Orsini, M. Corti, M. Mariani, L. Bordonali, C. Innocenti, C. Sangregorio, H. Oliveira, S. Lecommandoux, A. Lascialfari, O. SandreJournal of Material Chemistry B 1, 5317–5328. Link
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